Copolymerization of N-Carboxy-D and L-Alanine Anhydride
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Catalytic Stereoinversion of L-Alanine to Deuterated D-Alanine.
A combination of an achiral pyridoxal analogue and a chiral base has been developed for catalytic deuteration of L-alanine with inversion of stereochemistry to give deuterated D-alanine under mild conditions (neutral pD and 25 °C) without the use of any protecting groups. This system can also be used for catalytic deuteration of D-alanine with retention of stereochemistry to give deuterated D-a...
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ژورنال
عنوان ژورنال: The Journal of the Society of Chemical Industry, Japan
سال: 1966
ISSN: 0023-2734,2185-0860
DOI: 10.1246/nikkashi1898.69.127